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Due to the fact that starch (amylum) is a polysaccharide , a long chain compound consisting of glucose monomers it has poor solubility in most solvents. Some starches are water soluble because of the hydroxyl groups involved in the polysaccharide chain, some like the branched form amylopectin are more insoluble.
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Starch Soluble

Starch Soluble

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